ISOMERIZATION OF 1-HEXENE CATALYZED OVER POLYMER-SUPPORTED RUCL2(PPH3)3

Cited 1 time in webofscience Cited 0 time in scopus
  • Hit : 283
  • Download : 30
Polymer-supported ruthenium catalyst was prepared by anchoring dichlorotris(triphenylphosphine)ruthenium, RuCl2(PPh3)3, onto the phosphinated polystyrene bead. The polymer-supported RuCl2(PPh3)3 could be reused several times with only small loss of catalytic activity in the isomerization of 1-hexene. The activity rather increased during the few initial runs. In both homogeneous and heterogenized catalysts, an induction period was required to initiate the isomerization. The catalyst efficiency was promoted in the mixture of good swelling solvent and potent hydrogen donor. Upon heterogenizing, the activity was reduced by a factor of 2.0-8.2.
Publisher
KOREAN INSTITUTE CHEMICAL ENGINEERS
Issue Date
1991-07
Language
English
Article Type
Article
Citation

KOREAN JOURNAL OF CHEMICAL ENGINEERING, v.8, no.3, pp.183 - 187

ISSN
0256-1115
DOI
10.1007/BF02706681
URI
http://hdl.handle.net/10203/24194
Appears in Collection
CBE-Journal Papers(저널논문)
Files in This Item
This item is cited by other documents in WoS
⊙ Detail Information in WoSⓡ Click to see webofscience_button
⊙ Cited 1 items in WoS Click to see citing articles in records_button

qr_code

  • mendeley

    citeulike


rss_1.0 rss_2.0 atom_1.0