Ga-Doped Pt-Ni Octahedral Nanoparticles as a Highly Active and Durable Electrocatalyst for Oxygen Reduction Reaction

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Bimetallic PtNi nanoparticles have been considered as a promising electrocatalyst for oxygen reduction reaction (ORR) in polymer electrolyte membrane fuel cells (PEMFCs) owing to their high catalytic activity. However, under typical fuel cell operating conditions, Ni atoms easily dissolve into the electrolyte, resulting in degradation of the catalyst and the membrane-electrode assembly (MEA). Here, we report gallium-doped PtNi octahedral nanoparticles on a carbon support (Ga-PtNi/C). The Ga-PtNi/C shows high ORR activity, marking an 11.7-fold improvement in the mass activity (1.24 A mg(p)(t)(-1)) and a 17.3-fold improvement in the specific activity (2.53 mA cm(-2)) compared to the commercial Pt/C (0.106 A mg(p)(t)(-1) and 0.146 mA cm(-2)). Density functional theory calculations demonstrate that addition of Ga to octahedral PtNi can cause an increase in the oxygen intermediate binding energy, leading to the enhanced catalytic activity toward ORR. In a voltage-cycling test, the Ga-PtNi/C exhibits superior stability to PtNi/C and the commercial Pt/C, maintaining the initial Ni concentration and octahedral shape of the nanoparticles. Single cell using the Ga-PtNi/C exhibits higher initial performance and durability than those using the PtNi/C and the commercial Pt/C. The majority of the Ga-PtNi nanoparticles well maintain the octahedral shape without agglomeration after the single cell durability test (30,000 cycles). This work demonstrates that the octahedral Ga-PtNi/C can be utilized as a highly active and durable ORR catalyst in practical fuel cell applications.
Publisher
AMER CHEMICAL SOC
Issue Date
2018-04
Language
English
Article Type
Article
Keywords

MEMBRANE FUEL-CELLS; CATALYST DEGRADATION; ALLOY NANOPARTICLES; ANISOTROPIC GROWTH; TRANSITION-METALS; ENHANCED ACTIVITY; CATHODE CATALYST; PARTICLE-SIZE; IN-SITU; PLATINUM

Citation

NANO LETTERS, v.18, no.4, pp.2450 - 2458

ISSN
1530-6984
DOI
10.1021/acs.nanolett.8b00028
URI
http://hdl.handle.net/10203/241568
Appears in Collection
EEW-Journal Papers(저널논문)MS-Journal Papers(저널논문)
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