Tailoring the mechanical properties of sputter deposited nanotwinned nickel-molybdenum-tungsten films

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Advanced metallic alloys are attractive in microelectromechanical systems (MEMS) applications that require high density, electrical and thermal conductivity, strength, and dimensional stability. Here we report the mechanical behavior of direct current (DC) magnetron sputter deposited Nickel (Ni)-Molybdenum (Mo)-Tungsten (W) films annealed at various temperatures. The films deposit as single-phase nanotwinned solid solutions and possess ultra-high tensile strengths of approximately 3 GPa, but negligible ductility. Subsequent heat treatments resulted in grain growth and nucleation of Mo-rich precipitates. While films annealed at 600 °C or 800 °C for 1 h still showed brittle behavior, films annealed at 1,000 °C for 1 h were found to exhibit strength greater than 1.2 GPa and near 10% tensile ductility. In addition to the excellent mechanical properties, alloy films further exhibit remarkably improved dimensional stability – a lower coefficient of thermal expansion and greater microstructural stability. An excellent balance between mechanical properties and dimensional stability make sputter deposited Ni-Mo-W alloys promising structural materials for MEMS applications.
Publisher
PERGAMON-ELSEVIER SCIENCE LTD
Issue Date
2018-02
Language
English
Article Type
Article
Keywords

IRON-GROUP ALLOYS; THIN-FILMS; NANOCRYSTALLINE NI; GRAIN-BOUNDARY; MICROELECTROMECHANICAL SYSTEMS; ANOMALOUS CODEPOSITION; DEFORMATION MECHANISMS; THERMAL-STABILITY; SURFACE-DIFFUSION; MEMS APPLICATIONS

Citation

ACTA MATERIALIA, v.144, pp.216 - 225

ISSN
1359-6454
DOI
10.1016/j.actamat.2017.10.065
URI
http://hdl.handle.net/10203/240204
Appears in Collection
ME-Journal Papers(저널논문)
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