Supramolecular Nanotubules as a Catalytic Regulator for Palladium Cations: Applications in Selective Catalysis

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dc.contributor.authorWu, Shanshanko
dc.contributor.authorLi, Yongguangko
dc.contributor.authorXie, Siyingko
dc.contributor.authorMa, Congko
dc.contributor.authorLim, Joonwonko
dc.contributor.authorZhao, Jiongko
dc.contributor.authorKim, Dae Seokko
dc.contributor.authorYang, Minyongko
dc.contributor.authorYoon, Dong Kiko
dc.contributor.authorLee, Myongsooko
dc.contributor.authorKim, Sang Oukko
dc.contributor.authorHuang, Zhegangko
dc.date.accessioned2017-10-23T01:27:29Z-
dc.date.available2017-10-23T01:27:29Z-
dc.date.created2017-09-25-
dc.date.created2017-09-25-
dc.date.issued2017-09-
dc.identifier.citationANGEWANDTE CHEMIE-INTERNATIONAL EDITION, v.56, no.38, pp.11511 - 11514-
dc.identifier.issn1433-7851-
dc.identifier.urihttp://hdl.handle.net/10203/226289-
dc.description.abstractDespite the recent development of highly efficient and stable metal catalysts, conferral of regulatory characteristics to the catalytic reaction in heterogeneous systems remains a challenge. Novel supramolecular nanotubules were prepared by alternative stacking from trimeric macrocycles, which was found to be able to coordinate with Pd cations. The Pd complexes exhibited a high catalytic performance for C-C coupling reaction. Notably, the tubular catalyst was observed to be controlled by supramolecular reversible assembly and showed superior heterogeneous catalytic activity, which was maintained for a number of cycles or reuse under an aerobic environment. Furthermore, the supramolecular catalyst showed unprecedented selectivity for the multifunctional coupling reaction and was able to serve as a new constructor of asymmetrical compounds.-
dc.languageEnglish-
dc.publisherWILEY-V C H VERLAG GMBH-
dc.subjectELECTROLESS DEPOSITION-
dc.subjectMETAL NANOPARTICLES-
dc.subjectCOUPLING REACTIONS-
dc.subjectCARBON-
dc.subjectSUBSTRATE-
dc.subjectSURFACES-
dc.subjectCLUSTERS-
dc.subjectSUPPORT-
dc.subjectARRAYS-
dc.titleSupramolecular Nanotubules as a Catalytic Regulator for Palladium Cations: Applications in Selective Catalysis-
dc.typeArticle-
dc.identifier.wosid000409410700038-
dc.identifier.scopusid2-s2.0-85028876505-
dc.type.rimsART-
dc.citation.volume56-
dc.citation.issue38-
dc.citation.beginningpage11511-
dc.citation.endingpage11514-
dc.citation.publicationnameANGEWANDTE CHEMIE-INTERNATIONAL EDITION-
dc.identifier.doi10.1002/anie.201706373-
dc.contributor.localauthorYoon, Dong Ki-
dc.contributor.localauthorKim, Sang Ouk-
dc.contributor.nonIdAuthorWu, Shanshan-
dc.contributor.nonIdAuthorLi, Yongguang-
dc.contributor.nonIdAuthorXie, Siying-
dc.contributor.nonIdAuthorMa, Cong-
dc.contributor.nonIdAuthorZhao, Jiong-
dc.contributor.nonIdAuthorLee, Myongsoo-
dc.contributor.nonIdAuthorHuang, Zhegang-
dc.description.isOpenAccessN-
dc.type.journalArticleArticle-
dc.subject.keywordAuthorheterogeneous catalysis-
dc.subject.keywordAuthornanostructures-
dc.subject.keywordAuthorself-assembly-
dc.subject.keywordAuthorsupported catalysts-
dc.subject.keywordAuthorsupramolecular chemistry-
dc.subject.keywordPlusELECTROLESS DEPOSITION-
dc.subject.keywordPlusMETAL NANOPARTICLES-
dc.subject.keywordPlusCOUPLING REACTIONS-
dc.subject.keywordPlusCARBON-
dc.subject.keywordPlusSUBSTRATE-
dc.subject.keywordPlusSURFACES-
dc.subject.keywordPlusCLUSTERS-
dc.subject.keywordPlusSUPPORT-
dc.subject.keywordPlusARRAYS-
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