A T-Shaped Nickel(I) Metalloradical Species

A T-shaped Ni-I complex was synthesized using a rigid acridane-based pincer ligand to prepare a metalloradical center. Structural data displays a nickel ion is embedded in the plane of a PNP ligand. Having a sterically exposed half-filled d(x2-y2) orbital, this three-coordinate Ni-I species reveals unique open-shell reactivity including the homolytic cleavage of various sigma-bonds, such as H-H, N-N, and C-C.
Publisher
WILEY-V C H VERLAG GMBH
Issue Date
2017-08
Language
English
Keywords

CARBON BOND-CLEAVAGE; COMPLEXES; ACTIVATION; 3-COORDINATE; REACTIVITY; LIGAND; CHEMISTRY; AMMONIA; N-2; NI

Citation

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, v.56, no.32, pp.9502 - 9506

ISSN
1433-7851
DOI
10.1002/anie.201704487
URI
http://hdl.handle.net/10203/225664
Appears in Collection
CH-Journal Papers(저널논문)
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