Total Synthesis of (-)-Phorbaketal A

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dc.contributor.authorJoung, Seewonko
dc.contributor.authorKim, Rirako
dc.contributor.authorLee, Hee-Yoonko
dc.date.accessioned2017-08-23T06:39:26Z-
dc.date.available2017-08-23T06:39:26Z-
dc.date.created2017-08-21-
dc.date.created2017-08-21-
dc.date.created2017-08-21-
dc.date.issued2017-07-
dc.identifier.citationORGANIC LETTERS, v.19, no.14, pp.3903 - 3906-
dc.identifier.issn1523-7060-
dc.identifier.urihttp://hdl.handle.net/10203/225480-
dc.description.abstractA convergent asymmetric total synthesis of phorbaketal,A was achieved in 10 steps through a Au(I)-catalyzed intramolecular spiroketalization reaction of an alkyne, diol intermediate prepared from (R)-catvone and geranial. The spirciketalization reaction was ratio, and stereoselective and was accompanied by isomerization of an exo-olefin into the trisubstittned olefin to form a unique spiroketal structure of phorbaketals.-
dc.languageEnglish-
dc.publisherAMER CHEMICAL SOC-
dc.titleTotal Synthesis of (-)-Phorbaketal A-
dc.typeArticle-
dc.identifier.wosid000406356500055-
dc.identifier.scopusid2-s2.0-85025144624-
dc.type.rimsART-
dc.citation.volume19-
dc.citation.issue14-
dc.citation.beginningpage3903-
dc.citation.endingpage3906-
dc.citation.publicationnameORGANIC LETTERS-
dc.identifier.doi10.1021/acs.orglett.7b01797-
dc.contributor.localauthorLee, Hee-Yoon-
dc.description.isOpenAccessN-
dc.type.journalArticleArticle-
dc.subject.keywordPlusSPONGE PHORBAS SP-
dc.subject.keywordPlusAUSTRALIAN MARINE SPONGE-
dc.subject.keywordPlusALLYLIC ALCOHOLS-
dc.subject.keywordPlusNATURAL-PRODUCTS-
dc.subject.keywordPlusSTEREOSELECTIVE-SYNTHESIS-
dc.subject.keywordPlusPROMOTED REARRANGEMENT-
dc.subject.keywordPlusSTRUCTURE ELUCIDATION-
dc.subject.keywordPlusEFFICIENT ACCESS-
dc.subject.keywordPlusEPOXIDES-
dc.subject.keywordPlusSPIRASTRELLOLIDE-
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