Biomimetic total synthesis of (+/-)-berkeleyamide D

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We describe the total synthesis of (+/-)-berkeleyamide D using a biosynthetically inspired strategy. The spirocyclic core of berkeleyamide D was constructed via sequential epoxidations and a late-stage base-mediated cyclization of a biosynthetically relevant precursor. Our synthetic solution might be applicable to access other fungal natural products of this family.
Publisher
ROYAL SOC CHEMISTRY
Issue Date
2017-04
Language
English
Article Type
Article
Citation

ORGANIC CHEMISTRY FRONTIERS, v.4, no.4, pp.506 - 509

ISSN
2052-4129
DOI
10.1039/C6QO00812G
URI
http://hdl.handle.net/10203/223699
Appears in Collection
CH-Journal Papers(저널논문)
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