J-aggregation and disaggregation of indocyanine green in water

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J-aggregates of indocyanine green sodium iodide in water are formed by heat treatment. Starting from a dimeric solution the activation energy of molecule attachment(E-att approximate to 0.41 eV) to J-aggregates is determined by analysing the temperature dependence of the rate of J-aggregate absorption growth. The activation energy of molecule detachment (E-det approximate to 0.51 eV) from J-aggregates is deduced from the temperature dependent rate of J-aggregate absorption decrease after strong dilution. (C) 1997 Elsevier Science B.V
Publisher
ELSEVIER SCIENCE BV
Issue Date
1997-08
Language
English
Article Type
Article
Keywords

OPTICAL-PROPERTIES; RHODAMINE 6G; PSEUDOISOCYANINE; SPECTROSCOPY; EXCITONS; DYE; LINESHAPES; DYNAMICS; SPECTRA; LASER

Citation

CHEMICAL PHYSICS, v.220, no.3, pp.385 - 392

ISSN
0301-0104
DOI
10.1016/S0301-0104(97)00151-1
URI
http://hdl.handle.net/10203/212809
Appears in Collection
PH-Journal Papers(저널논문)
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