DC Field | Value | Language |
---|---|---|
dc.contributor.author | Song, Hyunjoon | ko |
dc.contributor.author | Lee, K | ko |
dc.contributor.author | Park, Joon Taik | ko |
dc.contributor.author | Choi, MG | ko |
dc.date.accessioned | 2010-12-23T06:16:25Z | - |
dc.date.available | 2010-12-23T06:16:25Z | - |
dc.date.created | 2012-02-06 | - |
dc.date.created | 2012-02-06 | - |
dc.date.issued | 1998-09 | - |
dc.identifier.citation | ORGANOMETALLICS, v.17, no.20, pp.4477 - 4483 | - |
dc.identifier.issn | 0276-7333 | - |
dc.identifier.uri | http://hdl.handle.net/10203/21212 | - |
dc.description.abstract | Two mu(3)-eta(2),eta(2),eta(2)-C-60 complexes, Os-3(CO)(8)(PPh3)(mu(3)-eta(2),eta(2),eta(2)-C-60) (8) and Os-3(CO)(7)(PMe3)(2)(mu(3)-eta(2),eta(2),eta(2)-C-60) (9), have been prepared by decarbonylation of Os-3(CO)(9)(mu(3)-eta(2),eta(2),eta(2)-C-60) (6) with Me3NO/MeCN in the presence of phosphine ligands. The molecular structure of 8 has been determined by a single-crystal X-ray diffraction study. The structure of 8 is derived from that of Os-3(CO)(11)(PPh3) by replacing three axial carbonyl ligands with a mu(3)-face-capping C-6 ring of C-60. The C-13 NMR spectra (C-60 region) of 6 and Os-3(CO)(8)(PMe3)(mu(3)-eta(2),eta(2),eta(2)-C-60) (7) show 11 sp(2) and 1 sp(3) carbon resonances and 29 sp(2) and 3 sp(3) carbon resonances, respectively, which are consistent with C-3v and C-s symmetric nature of the two complexes in solution. Electrochemical properties of 6, 7, and 9 have been studied by cyclic voltammetry (CV) in 1,2-dichlorobenzene (DCB) solutions. The general features of CV curves have revealed four reversible redox couples for 6 and 7 and three for 9 in the DCB potential window. The mu(3)-eta(2),eta(2),eta(2)-C-60 complexes, 6, 7, and 9, show a remarkable electrochemical stability compared to the known eta(2)-C-60 triosmium carbonyl complexes. The CV results suggest that a C-60-mediated electron transfer to the triosmium center takes place in 6 and 7, but three successive C-60-localized reductions occur in 9. | - |
dc.description.sponsorship | We are grateful to the Korea Advanced Institute of Science and Technology (KAIST) for financial support of this research. We thank Prof. J. Kwak at KAIST for help in electrochemical measurements. | en |
dc.language | English | - |
dc.language.iso | en_US | en |
dc.publisher | AMER CHEMICAL SOC | - |
dc.subject | BUCKMINSTERFULLERENE C-60 | - |
dc.subject | DERIVATIVES | - |
dc.subject | CLUSTER | - |
dc.subject | CARBONYL | - |
dc.subject | 60> | - |
dc.subject | FULLERENE | - |
dc.title | Synthesis, structure, and electrochemical studies of mu(3)-eta(2),eta(2),eta(2)-C-60 triosmium complexes | - |
dc.type | Article | - |
dc.identifier.wosid | 000076397600026 | - |
dc.identifier.scopusid | 2-s2.0-0000024002 | - |
dc.type.rims | ART | - |
dc.citation.volume | 17 | - |
dc.citation.issue | 20 | - |
dc.citation.beginningpage | 4477 | - |
dc.citation.endingpage | 4483 | - |
dc.citation.publicationname | ORGANOMETALLICS | - |
dc.embargo.liftdate | 9999-12-31 | - |
dc.embargo.terms | 9999-12-31 | - |
dc.contributor.localauthor | Song, Hyunjoon | - |
dc.contributor.localauthor | Park, Joon Taik | - |
dc.contributor.nonIdAuthor | Lee, K | - |
dc.contributor.nonIdAuthor | Choi, MG | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordPlus | BUCKMINSTERFULLERENE C-60 | - |
dc.subject.keywordPlus | DERIVATIVES | - |
dc.subject.keywordPlus | CLUSTER | - |
dc.subject.keywordPlus | CARBONYL | - |
dc.subject.keywordPlus | 60> | - |
dc.subject.keywordPlus | FULLERENE | - |
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