Heterolytic H-2 Cleavage and Catalytic Hydrogenation by an Iron Metallaboratrane

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Reversible, heterolytic addition of H-2 across an iron boron bond in a ferraboratrane with formal hydride transfer to the boron gives iron-borohydrido-hydride complexes. These compounds catalyze the hydrogenation of alkenes and alkynes to the respective alkanes.. Notably, the boron is capable of acting as a shuttle for hydride transfer to substrates. The results are interesting in the context of heterolytic substrate addition across metal boron bonds in metallaboratranes and related systems, as well as metal ligand bifunctional catalysis.
Publisher
AMER CHEMICAL SOC
Issue Date
2013-05
Language
English
Article Type
Article
Citation

ORGANOMETALLICS, v.32, no.10, pp.3053 - 3062

ISSN
0276-7333
DOI
10.1021/om400281v
URI
http://hdl.handle.net/10203/211907
Appears in Collection
CH-Journal Papers(저널논문)
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