Rhodium-Catalyzed Direct C-H Phosphorylation of (Hetero)arenes Suitable for Late-Stage Functionalization

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Efficient rhodium-catalyzed direct C-H phosphorylation of (hetero)arenes was developed. Various directing groups and a wide range of substrates, including heterocycles, can be utilized in this C-H phosphorylation process, allowing for the rapid installation of the phosphonate group into medicinally and biologically important privileged scaffolds. The efficient and straightforward method could serve as a new tool to streamline late-stage C-H functionalization for preparing aryl phosphonates, which are important structural motif in synthetic and medicinal chemistry
Publisher
WILEY-V C H VERLAG GMBH
Issue Date
2016-04
Language
English
Article Type
Article
Keywords

CARBON-HYDROGEN BONDS; HETEROAROMATIC-COMPOUNDS; C(SP(2))-H BONDS; PHOSPHINE OXIDES; ACTIVATION; ALKYNES; ALKENES; ARENES; ACIDS; ARYL

Citation

ADVANCED SYNTHESIS & CATALYSIS, v.358, no.8, pp.1296 - 1301

ISSN
1615-4150
DOI
10.1002/adsc.201600014
URI
http://hdl.handle.net/10203/209171
Appears in Collection
CH-Journal Papers(저널논문)
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