Poly(phenylnorbornene) from Ring-Opening Metathesis and Its Hydrogenated Derivatives

Cited 9 time in webofscience Cited 0 time in scopus
  • Hit : 394
  • Download : 0
DC FieldValueLanguage
dc.contributor.authorLi, Shengko
dc.contributor.authorBurns, Adam B.ko
dc.contributor.authorRegister, Richard A.ko
dc.contributor.authorBell, Andrewko
dc.date.accessioned2016-05-16T04:33:35Z-
dc.date.available2016-05-16T04:33:35Z-
dc.date.created2016-02-03-
dc.date.created2016-02-03-
dc.date.issued2012-10-
dc.identifier.citationMACROMOLECULAR CHEMISTRY AND PHYSICS, v.213, no.19, pp.2027 - 2033-
dc.identifier.issn1022-1352-
dc.identifier.urihttp://hdl.handle.net/10203/207380-
dc.description.abstractNovel polymers are synthesized from 5-phenyl-2-norbornene (PhNb) and its saturated side group analog, 5-cyclohexyl-2-norbornene, using ring-opening metathesis polymerization (ROMP). Polymers of both endo-rich and all-exo PhNb show glass transition temperatures (Tg) = 88 +/- 1 degrees C, indicating a negligible effect of monomer stereoisomerism on segmental packing or the energy barriers to motion at the glass transition, despite the substantial size of the side group. Post-polymerization hydrogenation of the PhNb polymers using catalysts with different selectivities reveals that saturation of the backbone produces a 17 degrees C decrease in Tg (for both aromatic and cycloaliphatic side groups), whereas saturation of the side groups produces a 14 degrees C increase in Tg (for both saturated and unsaturated backbones).-
dc.languageEnglish-
dc.publisherWILEY-V C H VERLAG GMBH-
dc.subjectALKYL NORBORNENE DICARBOXYIMIDES-
dc.subjectGLASS-TRANSITION TEMPERATURE-
dc.subjectWELL-DEFINED INITIATORS-
dc.subjectMOLECULAR-WEIGHT-
dc.subjectPOLYMERIZATION-
dc.subjectCOMPLEXES-
dc.subjectCATALYSTS-
dc.subjectPOLYMERS-
dc.subjectPOLY(1,3-CYCLOPENTYLENEVINYLENE)-
dc.subjectPOLY(VINYLCYCLOHEXANE)-
dc.titlePoly(phenylnorbornene) from Ring-Opening Metathesis and Its Hydrogenated Derivatives-
dc.typeArticle-
dc.identifier.wosid000309449800006-
dc.identifier.scopusid2-s2.0-84867206461-
dc.type.rimsART-
dc.citation.volume213-
dc.citation.issue19-
dc.citation.beginningpage2027-
dc.citation.endingpage2033-
dc.citation.publicationnameMACROMOLECULAR CHEMISTRY AND PHYSICS-
dc.identifier.doi10.1002/macp.201200294-
dc.contributor.localauthorLi, Sheng-
dc.contributor.nonIdAuthorBurns, Adam B.-
dc.contributor.nonIdAuthorRegister, Richard A.-
dc.contributor.nonIdAuthorBell, Andrew-
dc.type.journalArticleArticle-
dc.subject.keywordAuthorglass transition-
dc.subject.keywordAuthorisomer-
dc.subject.keywordAuthorisomerization-
dc.subject.keywordAuthorliving polymerization-
dc.subject.keywordAuthornoncrystalline polymers-
dc.subject.keywordAuthorring-opening metathesis polymerization-
dc.subject.keywordPlusALKYL NORBORNENE DICARBOXYIMIDES-
dc.subject.keywordPlusGLASS-TRANSITION TEMPERATURE-
dc.subject.keywordPlusWELL-DEFINED INITIATORS-
dc.subject.keywordPlusMOLECULAR-WEIGHT-
dc.subject.keywordPlusPOLYMERIZATION-
dc.subject.keywordPlusCOMPLEXES-
dc.subject.keywordPlusCATALYSTS-
dc.subject.keywordPlusPOLYMERS-
dc.subject.keywordPlusPOLY(1,3-CYCLOPENTYLENEVINYLENE)-
dc.subject.keywordPlusPOLY(VINYLCYCLOHEXANE)-
Appears in Collection
CBE-Journal Papers(저널논문)
Files in This Item
There are no files associated with this item.
This item is cited by other documents in WoS
⊙ Detail Information in WoSⓡ Click to see webofscience_button
⊙ Cited 9 items in WoS Click to see citing articles in records_button

qr_code

  • mendeley

    citeulike


rss_1.0 rss_2.0 atom_1.0