DC Field | Value | Language |
---|---|---|
dc.contributor.author | Choi, Kyung Min | ko |
dc.contributor.author | Park, Jung Hyo | ko |
dc.contributor.author | Kang, Jeung Ku | ko |
dc.date.accessioned | 2016-04-20T07:01:52Z | - |
dc.date.available | 2016-04-20T07:01:52Z | - |
dc.date.created | 2015-09-01 | - |
dc.date.created | 2015-09-01 | - |
dc.date.created | 2015-09-01 | - |
dc.date.issued | 2015-07 | - |
dc.identifier.citation | CHEMISTRY OF MATERIALS, v.27, no.14, pp.5088 - 5093 | - |
dc.identifier.issn | 0897-4756 | - |
dc.identifier.uri | http://hdl.handle.net/10203/205644 | - |
dc.description.abstract | A metal-organic framework (MOP) with a specific construction and pores was demonstrated to have many advanced properties, but still limited to having unique aspects arising from the combination of different MOFs in a single body. Here, we report a facile method to produce MOF-5 crystals with nanocrystalline HKUST-1 (nHKUST-1) embedded into them in what is termed the "nHKUST-1 subset of MOF-5" structure. The results show that the nHKUST-1 subset of MOF-5 structure is capable of Molecular encapsulation by trapping dye molecules in nHKUST-1 particles and embedding them in MOF-5 crystals. Moreover, the gravimetric uptake capacity of nHKUST-1 subset of MOF-5 for methane (CH4) was found to be enhanced as compared to that of MOF-5 or nHKUST-1 alone such that the nHKUST-1 subset of MOF-5 structure exhibits a volumetric capacity of 250% for fuel storage deliverable by the CNG tank at room temperature and 80 bar. Furthermore, it showed robust capacity retention for reversible CH4 uptake cycles at room temperature. | - |
dc.language | English | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.title | Nanocrystalline MOFs Embedded in the Crystals of Other MOFs and Their Multifunctional Performance for Molecular Encapsulation and Energy-Carrier Storage | - |
dc.type | Article | - |
dc.identifier.wosid | 000358823000026 | - |
dc.identifier.scopusid | 2-s2.0-84937824392 | - |
dc.type.rims | ART | - |
dc.citation.volume | 27 | - |
dc.citation.issue | 14 | - |
dc.citation.beginningpage | 5088 | - |
dc.citation.endingpage | 5093 | - |
dc.citation.publicationname | CHEMISTRY OF MATERIALS | - |
dc.identifier.doi | 10.1021/acs.chemmater.5b01786 | - |
dc.contributor.localauthor | Kang, Jeung Ku | - |
dc.description.isOpenAccess | N | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordPlus | METAL-ORGANIC-FRAMEWORK | - |
dc.subject.keywordPlus | CORE-SHELL | - |
dc.subject.keywordPlus | ALLOY NANOPARTICLES | - |
dc.subject.keywordPlus | HYDROGEN STORAGE | - |
dc.subject.keywordPlus | FORMIC-ACID | - |
dc.subject.keywordPlus | REDUCTION | - |
dc.subject.keywordPlus | DEHYDROGENATION | - |
dc.subject.keywordPlus | CATALYSIS | - |
dc.subject.keywordPlus | OXIDATION | - |
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