Stereocontrolled Synthesis of the C1-C10 Fragments of Monensin B and Laidlomycin

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An efficient synthetic route to the C1-C10 fragments of laidlomycin and monensin B has been developed toward their total synthesis. The asymmetric carbons have been elaborated by a syn-aldol reaction using the oxazolidinone chiral auxiliary for C6 and C7, an anti-aldol reaction for C3 and C4, the Tishchenko-Evans reaction for C5, and a chiral building block for C2.
Publisher
WILEY-V C H VERLAG GMBH
Issue Date
2015-06
Language
English
Article Type
Article
Citation

ASIAN JOURNAL OF ORGANIC CHEMISTRY, v.4, no.6, pp.567 - 572

ISSN
2193-5807
DOI
10.1002/ajoc.201500078
URI
http://hdl.handle.net/10203/199775
Appears in Collection
CH-Journal Papers(저널논문)
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