Iridium(III)-Catalyzed C-H Amidation of Arylphosphoryls Leading to a P-Stereogenic Center

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Direct C-H amidation of arylphosphoryl compounds has been developed by using an Ir-III catalyst system under mild conditions. A wide range of substrates could be employed with high functional-group tolerance. This procedure was successfully applied for the first time to the asymmetric reaction giving rise to a P-chirogenic center with a high diastereomeric ratio of up to 19:1 (90% de).
Publisher
WILEY-V C H VERLAG GMBH
Issue Date
2014-09
Language
English
Article Type
Article
Keywords

CARBON-HYDROGEN BONDS; PHOSPHORUS-COMPOUNDS; ASYMMETRIC-SYNTHESIS; NATURAL-PRODUCTS; NITROGEN-SOURCE; ACTIVATION; ARYLATION; ARENES; AZIDES; FUNCTIONALIZATION

Citation

CHEMISTRY-A EUROPEAN JOURNAL, v.20, no.39, pp.12421 - 12425

ISSN
0947-6539
DOI
10.1002/chem.201404151
URI
http://hdl.handle.net/10203/194526
Appears in Collection
CH-Journal Papers(저널논문)
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