Production of nitrogen-doped graphite from carbon dioxide using polyaminoborane

Cited 7 time in webofscience Cited 0 time in scopus
  • Hit : 145
  • Download : 7
Nitrogen-doped graphite was prepared from gaseous carbon dioxide (CO2) under moderate conditions by polyaminoborane (PAB). This conversion was achieved in a two-step process: CO2 reacted with PAB under mild temperature (<115 degrees C) and low CO2 pressure (<3.10 MPa) to form a solid product containing formate (-OOCH), methoxy (-OCH3), and aliphatic groups; then pyrolysis of this solid product at temperatures up to 750 degrees C under an inert N-2 atmosphere produced a black carbon material. Raman spectroscopic and high-resolution scanning electron microscopic investigations confirmed the multi-layer graphitic structure of this carbon material. Incorporation of nitrogen atoms into the carbon lattice was further detected by X-ray photoelectron spectroscopy (XPS). This work presents the production of nitrogen-doped graphite from gaseous CO2 under mild conditions and provides one feasible option for CO2 capture and conversion at low costs.
Publisher
ROYAL SOC CHEMISTRY
Issue Date
2013-10
Language
English
Article Type
Article
Keywords

X-RAY PHOTOELECTRON; NITRIDE FILMS; BORON-NITRIDE; OXYGEN REDUCTION; AMMONIA BORANE; POROUS CARBON; GRAPHENE; LITHIUM; SODIUM; SPECTROSCOPY

Citation

RSC ADVANCES, v.3, no.48, pp.25752 - 25757

ISSN
2046-2069
DOI
10.1039/c3ra44288h
URI
http://hdl.handle.net/10203/188637
Appears in Collection
CBE-Journal Papers(저널논문)
Files in This Item
This item is cited by other documents in WoS
⊙ Detail Information in WoSⓡ Click to see webofscience_button
⊙ Cited 7 items in WoS Click to see citing articles in records_button

qr_code

  • mendeley

    citeulike


rss_1.0 rss_2.0 atom_1.0