Study on the enhanced high power performance of lithium-ion battery = 셀룰로오스 주형을 사용하여 합성된 리튬 이온전지 양극의 향상된 고출력 성능에 대한 연구

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After successful commercialization of small-sized lithium-ion batteries in portable electronics by Sony at 1991, new area of research and market which needs advanced performance of lithium-ion batteries is arising such as electric vehicle and hybrid electric vehicle. In the area, increased specific capacity of lithium-ion battery is very important, but enhanced high power performance is also significant and more complicated to be achieved. To improve the performance of lithium-ion batteries, when material is fixed, increasing electric conductivity or reducing ion diffusion length in solid phase is necessary. In this study, we focus on the reducing pathway of lithium ions in active materials. There have been a lot of researches to achieve it by synthesizing nanoparticle, nanorod, and nanowire and so on. However, in the purpose of mass production, only nanoparticle has an advantage in their preparation, because nanorod and nanowire need delicate and sensitive synthesis process which hinders large scale production of them. Even though nanoparticle has a merit in their production process, this form also has a problem of agglomeration when it is mixed with con-ducting agent and binder to cast on current collector. To solve all these problems, we used cellulose (cotton) as a template to synthesis nanoparticle but not to make them agglomerate by aligning them to form nanoparticle fiber structure. We believe that this form will enhance high power performance of lithium ion battery when this method is applied to synthesis of electrode active material. Therefore, we prepared LiCoO2 cathode active material by this cotton method and compared it with commercial LiCoO2 in SEM, XRD, BET and electrochemical tests especially for high rate performance. After comparison, excellent high power performance of LiCoO2 nanoparticle fibers was confirmed.
Advisors
Park, Jung-Kiresearcher박정기
Description
한국과학기술원 : 생명화학공학과,
Publisher
한국과학기술원
Issue Date
2012
Identifier
509369/325007  / 020104441
Language
eng
Description

학위논문(석사) - 한국과학기술원 : 생명화학공학과, 2012.8, [ viii, 49 p. ]

Keywords

cathode; Lithium-ion Battery; LiCoO2; cotton; high power performance; 리튬이차전지; 양극; 솜; 고출력 성능; 나노입자섬유; nanoparticle fiber

URI
http://hdl.handle.net/10203/179990
Link
http://library.kaist.ac.kr/search/detail/view.do?bibCtrlNo=509369&flag=dissertation
Appears in Collection
CBE-Theses_Master(석사논문)
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