이액상계를 이용한 토양슬러리 반응기에서의 PAH 거동 특성

Abstract

In this study, the mass transfer behaviors of phenanthrene, anthracene, and pyrene in soil slurry reactor (SSR) using two-liquid phase (TLP) system were investigated. The mass transfer ratio and rate of PAH in the TLP system using light paraffine oil, which has the highest solubility of PAH, were influenced by the amount of light paraffine oil and mixing speed. When the amount of light paraffine oil decreased from 15 % to 2.5 % (v/v), the mass transfer ratio of anthracene decreased significantly compared with that of phenanthrene and pyrene. As mixing speed increased, the initial mass transfer rate of PAH within 1 day was enhanced. However, each final mass transfer ratio of three PAHs after 5 day was similar irrespective of mixing speed.