Surface-initiated, enzymatic polymerization of biodegradable polyesters

Enzyme-catalyzed, ring-opening polymerization of biodegradable aliphatic polyesters has successfully been applied to surface-initiated polymerization (see Figure). Using lipase B as a catalyst, a thin film of poly (epsilon-caprolactone) (PCL) and poly(p-dioxanone) (PPDX) on a gold substrate (after a formation of self-assembled monolayers terminating in hydroxyl groups) is formed.
Publisher
WILEY-V C H VERLAG GMBH
Issue Date
2003-12
Language
ENG
Keywords

SELF-ASSEMBLED MONOLAYERS; OPENING METATHESIS POLYMERIZATION; TRANSFER RADICAL POLYMERIZATION; CATIONIC-POLYMERIZATION; AMBIENT-TEMPERATURE; GOLD NANOPARTICLES; SILICON SURFACES; AQUEOUS-MEDIA; POLYMERS; BRUSHES

Citation

ADVANCED MATERIALS, v.15, no.24, pp.2063 - +

ISSN
0935-9648
URI
http://hdl.handle.net/10203/13079
Appears in Collection
CH-Journal Papers(저널논문)
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