Cooperative Assembly of Block Copolymers with Deformable Interfaces: Toward Nanostructured Particles

Block copolymers confined in emulsion droplets self-organize into polymeric particles, and cooperative self-assembly driven by deformable interfacial properties produces unprecedented structural motifs such as prolates of stacked lamellae, oblates with biomimetic nanoscale architecture, and spheres with tori or helices (see figure). Interface-mediated structural evolution provides a novel route for synthesizing functional particles with unique nanostructures.
Publisher
WILEY-V C H VERLAG GMBH
Issue Date
2008-11
Language
ENG
Keywords

DIBLOCK COPOLYMERS; THIN-FILMS; CONFINEMENT; NUCLEATION; MICROPHASE; SURFACES; KINETICS; BLENDS; PHASE

Citation

ADVANCED MATERIALS, v.20, no.21, pp.4103 - 4103

ISSN
0935-9648
DOI
10.1002/adma.200801377
URI
http://hdl.handle.net/10203/12680
Appears in Collection
CBE-Journal Papers(저널논문)
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