Self-assembly of hydrogen-bonded polymeric rods based on the cyanuric acid center dot melamine lattice

This paper describes the self-assembly of hydrogen-bonded polymeric rods based on the lattice of cyanuric acid and melamine (CA . M). Data from H-1 NMR spectroscopy, IR spectroscopy, gel permeation chromatography (GPC), and transmission electron microscopy (TEM) are interpreted as indicating that the self-assembly of a bisisocyanuric acid (bisCA) and a bismelamine (bisM) formed polymeric nanorods [(bisCA)(n)(bisM)(n)] composed of parallel CA . M rosettes. The TEM results suggest that these rods aggregate as bundles. The length of the bundles ranged from 100 to 1500 nm, and their diameter was in the range from 15 to 500 nm.
Publisher
AMER CHEMICAL SOC
Issue Date
1999-03
Language
ENG
Keywords

NANOSCALE TUBULAR ENSEMBLES; NONCOVALENT SYNTHESIS; SUPRAMOLECULAR CHEMISTRY; H-1-NMR SPECTROSCOPY; PEPTIDE NANOTUBES; BILAYER-MEMBRANES; ORGANIC FIBERS; MOLECULES; NANOSTRUCTURES; ORGANIZATION

Citation

CHEMISTRY OF MATERIALS, v.11, no.3, pp.684 - 690

ISSN
0897-4756
DOI
10.1021/cm980540j
URI
http://hdl.handle.net/10203/12171
Appears in Collection
CH-Journal Papers(저널논문)
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