Total synthesis of (-)-dysiherbaine

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The enantioselective synthesis of (-)-dysiherbaine (1) has been established with efficiency via a unique synthetic strategy involving the desymmetrization of 2-substituted glycerol to install a quaternary chiral carbon, which induces further stereochemistry in the bicyclic perhydrofuropyran through mercuriocyclization and epoxidation.
Publisher
ROYAL SOC CHEMISTRY
Issue Date
2012
Language
English
Article Type
Article
Keywords

RECEPTOR ION CHANNELS; SPONGE DYSIDEA-HERBACEA; EXCITATORY AMINO-ACIDS; TETHERED AMINOHYDROXYLATION; MARINE SPONGE; STEREOSELECTIVE SYNTHESIS; GLUTAMATE RECEPTORS; KAINATE RECEPTORS; DYSIHERBAINE; CORE

Citation

CHEMICAL COMMUNICATIONS, v.48, no.50, pp.6295 - 6297

ISSN
1359-7345
DOI
10.1039/c2cc32736h
URI
http://hdl.handle.net/10203/103749
Appears in Collection
CH-Journal Papers(저널논문)
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