A Polar and Chiral Indium Telluride Featuring Supertetrahedral T2 Clusters and Nonlinear Optical Second Harmonic Generation
The "KIn(2)" Zintl phase activates tellurium under solvothermal conditions and yields the compound {[In(en)(3)][In(5)Te(9)(en)(2)] center dot 0.5en}(n) (en = ethylenediamine). The material has both a polar and chiral layered framework and exhibits type 1 phase-matchable strong second harmonic generation (SHG) response.
- Publisher
- AMER CHEMICAL SOC
- Issue Date
- 2009-01
- Language
- English
- Article Type
- Article
- Keywords
OPEN-FRAMEWORK CHALCOGENIDES; CRYSTAL-STRUCTURE; SOLID-STATE; ELECTROCHEMICAL SYNTHESIS; METAL POLYCHALCOGENIDES; COORDINATION CHEMISTRY; SOLVOTHERMAL SYNTHESIS; ZINTL ION; SULFIDE; ANIONS
- Citation
CHEMISTRY OF MATERIALS, v.21, no.1, pp.12 - 14
- ISSN
- 0897-4756
- Appears in Collection
- NT-Journal Papers(저널논문)
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