A Polar and Chiral Indium Telluride Featuring Supertetrahedral T2 Clusters and Nonlinear Optical Second Harmonic Generation

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The "KIn(2)" Zintl phase activates tellurium under solvothermal conditions and yields the compound {[In(en)(3)][In(5)Te(9)(en)(2)] center dot 0.5en}(n) (en = ethylenediamine). The material has both a polar and chiral layered framework and exhibits type 1 phase-matchable strong second harmonic generation (SHG) response.
Publisher
AMER CHEMICAL SOC
Issue Date
2009-01
Language
English
Article Type
Article
Keywords

OPEN-FRAMEWORK CHALCOGENIDES; CRYSTAL-STRUCTURE; SOLID-STATE; ELECTROCHEMICAL SYNTHESIS; METAL POLYCHALCOGENIDES; COORDINATION CHEMISTRY; SOLVOTHERMAL SYNTHESIS; ZINTL ION; SULFIDE; ANIONS

Citation

CHEMISTRY OF MATERIALS, v.21, no.1, pp.12 - 14

ISSN
0897-4756
DOI
10.1021/cm8027516
URI
http://hdl.handle.net/10203/103206
Appears in Collection
NT-Journal Papers(저널논문)
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