Thermally stable iron based redox catalysts for the thermo-chemical hydrogen generation from water

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Redox materials with high thermal stabilities, comprising iron oxide with alumina were synthesized from ultrasonic spray pyrolysis method. Their catalytic activities towards the redox evolution of hydrogen from water were evaluated and compared with that of pure iron oxide, which decreased rapidly after 1 cycle due to its low thermal stability. The samples containing alumina sustained their total and relative hydrogen evolutions over three redox cycles, while maintaining their original surface morphologies, thus demonstrating their thermal stability. (C) 2012 Elsevier Ltd. All rights reserved.
Publisher
PERGAMON-ELSEVIER SCIENCE LTD
Issue Date
2012-06
Language
English
Article Type
Article
Keywords

AQUEOUS-METHANOL SOLUTION; SPRAY-PYROLYSIS; ALUMINA PARTICLES; H-2 GENERATION; CYCLES; OXIDE; EVOLUTION; FERRITES; ZIRCONIA; SYSTEM

Citation

ENERGY, v.42, no.1, pp.313 - 320

ISSN
0360-5442
DOI
10.1016/j.energy.2012.03.051
URI
http://hdl.handle.net/10203/102318
Appears in Collection
CBE-Journal Papers(저널논문)
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